Liu, Guosheng----State Key Laboratory of Organometallic Chemistry 345 Lingling Lu, Shanghai

Liu, Guosheng Professor

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry, CAS

345 Lingling Lu, Shanghai 200032

Phone: +86 21 54925346

Fax: +86 21 64166128

Education:

09/1999 - 06/2002　 Ph.D, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, China. (Supervisor: Prof. Xiyan Lu)

09/1996 - 06/1999　M.S, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, China (Supervisor: Prof. Zhuo Zheng)

09/1991 - 06/1995　B.S, Nanjing University of Science and Technology, Nanjing, China

Research Experience:

08/2007 - present　Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, China

08/2005 - 06/2007 Postdoctoral Fellow, Department of Chemistry, University of Wisconsin - Madison, Madison, WI. USA (with professor Shannon Stahl)

03/2003 - 06/2005 Postdoctoral Fellow, Department of Chemistry, Lehigh University, Bethlehem, PA, USA (with professor Li Jia)

Research Interests:

transition-metal catalyzed synthetic methodology and related mechanistic studies

Transition-metal involved green oxidation

Biodegradable polymers synthesis based on utilizing CO and CO₂

Selected Publications:

1. Yin, Guoyin; Wu, Yichen; Liu, Guosheng* “Scope and Mechanism of Allylic C-H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)₂ Catalyst System: Insights into the Effect of Naphthoquinone”, J. Am. Chem. Soc. 2010, 132, 11978-11987.

2. Qiu, Shuifa; Xu, Tao; Zhou, Juan; Guo, Yanlong; Liu, Guosheng* “Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes”, J. Am. Chem. Soc. 2010, 132, 2856-2857.

3. Wu, Tao; Yin, Guoyin; Liu, Guosheng* “Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes”, J. Am. Chem. Soc. 2009, 131, 16354-16355.

4. Wu, Liang; Qiu, Shuifa; Liu, Guosheng* “Br？nsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett. 2009, 11, 2707.

5. Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J. 2009, 15, 2751.

6. Liu, Guosheng*; Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: efficient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed. 2008, 47, 4733.

7. Yin, Guoyin; Liu, Guosheng* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed. 2008, 47, 5442. (Featured in Synfact, 2008, 10, 1066)

8. Wu, Yicheng; Liu, Guosheng* “Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins”, Top. Cur. Chem. 2010 (in press).

9. Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li* “Cobalt-Catalyzed Carbonylative Polymerization of Azetidines.” Macromolecules 2008, 41, 8980.

10. Liu, Guosheng; Stahl, Shannon. S* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc. 2007, 129, 6328-6335.

11. Liu, Guosheng; Stahl, Shannon. S* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN₂ C-O Bond Formation”, J. Am. Chem. Soc. 2006, 128, 7179-7181.

12. Liu, Guosheng; Jia, Li* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed. 2006, 45, 129-131.

13. Liu, Guosheng; Jia, Li* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc. 2004, 126, 14716.