Liu, Guosheng   Professor

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry, CAS

345 Lingling Lu, Shanghai 200032

Phone: +86 21 54925346

Fax: +86 21 64166128

Email: gliu@sioc.ac.cn

Education:

09/1999 - 06/2002  Ph.D, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, China. (Supervisor: Prof. Xiyan Lu)

09/1996 - 06/1999 M.S, Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, China (Supervisor: Prof. Zhuo Zheng)

09/1991 - 06/1995 B.S, Nanjing University of Science and Technology, Nanjing, China

 

Research Experience:

08/2007 - present Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Science, Shanghai, China

08/2005 - 06/2007  Postdoctoral Fellow, Department of Chemistry, University of Wisconsin - Madison, Madison, WI. USA (with professor Shannon Stahl)

03/2003 - 06/2005  Postdoctoral Fellow, Department of Chemistry, Lehigh University, Bethlehem, PA, USA (with professor Li Jia)

Research Interests:

transition-metal catalyzed synthetic methodology and related mechanistic studies

Transition-metal involved green oxidation

Biodegradable polymers synthesis based on utilizing CO and CO2

Selected Publications:

1. Yin, Guoyin; Wu, Yichen; Liu, Guosheng* “Scope and Mechanism of Allylic C-H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2 Catalyst System: Insights into the Effect of Naphthoquinone”, J. Am. Chem. Soc. 2010, 132, 11978-11987.

2. Qiu, Shuifa; Xu, Tao; Zhou, Juan; Guo, Yanlong; Liu, Guosheng* “Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes”, J. Am. Chem. Soc. 2010, 132, 2856-2857.

3. Wu, Tao; Yin, Guoyin; Liu, Guosheng* “Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes”, J. Am. Chem. Soc. 2009, 131, 16354-16355.

4. Wu, Liang; Qiu, Shuifa; Liu, Guosheng* “Brønsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.” Org. Lett. 2009, 11, 2707.

5. Qiu, Shuifa; Wei, Yunyang; Liu, Guosheng* “Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.” Chem. Eur. J. 2009, 15, 2751.

6. Liu, Guosheng*; Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: efficient synthesis of linear allylamine derivatives.” Angew. Chem. Int. Ed. 2008, 47, 4733.

7. Yin, Guoyin; Liu, Guosheng* “Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.” Angew. Chem. Int. Ed. 2008, 47, 5442. (Featured in Synfact, 2008, 10, 1066)

8. Wu, Yicheng; Liu, Guosheng* “Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins”, Top. Cur. Chem. 2010 (in press).

9. Chai, Jianfang; Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li* “Cobalt-Catalyzed Carbonylative Polymerization of Azetidines.” Macromolecules 2008, 41, 8980.

10. Liu, Guosheng; Stahl, Shannon. S* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.” J. Am. Chem. Soc. 2007, 129, 6328-6335.

11. Liu, Guosheng; Stahl, Shannon. S* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN2 C-O Bond Formation”, J. Am. Chem. Soc. 2006, 128, 7179-7181.

12. Liu, Guosheng; Jia, Li* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”, Angw. Chem. Int. Ed. 2006, 45, 129-131.

13. Liu, Guosheng; Jia, Li* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”, J. Am. Chem. Soc. 2004, 126, 14716.