Liu, Guosheng   Professor

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry, CAS

345 Lingling Lu, Shanghai 200032

Phone: +86 21 54925346

Fax: +86 21 64166128

Email:gliu@sioc.ac.cn

Education:

09/1999 - 06/2002　 Ph.D, Shanghai Institute of Organic Chemistry, Chinese Academy of Science,Shanghai, China. (Supervisor: Prof. Xiyan Lu)

09/1996 - 06/1999　M.S, Dalian Institute of Chemical Physics, Chinese Academy of Science,Dalian, China (Supervisor: Prof. Zhuo Zheng)

09/1991 - 06/1995　B.S, Nanjing University of Science and Technology, Nanjing, China

Research Experience:

08/2007 - present　Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute ofOrganic Chemistry, Chinese Academy of Science, Shanghai, China

08/2005 - 06/2007  Postdoctoral Fellow, Department of Chemistry, University of Wisconsin -Madison, Madison, WI. USA (with professor Shannon Stahl)

03/2003 - 06/2005  Postdoctoral Fellow, Department of Chemistry, Lehigh University, Bethlehem,PA, USA (with professor Li Jia)

Research Interests:

transition-metal catalyzed synthetic methodology and related mechanistic studies

Transition-metal involved green oxidation

Biodegradable polymers synthesis based on utilizing CO and CO₂

Selected Publications:

1.Yin, Guoyin; Wu, Yichen;Liu, Guosheng*“Scope and Mechanism of Allylic C-H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)₂Catalyst System: Insights into the Effect of Naphthoquinone”,J. Am. Chem. Soc.2010,132, 11978-11987.

2.Qiu, Shuifa; Xu, Tao; Zhou, Juan; Guo, Yanlong;Liu, Guosheng*“Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes”,J. Am. Chem. Soc.2010,132, 2856-2857.

3.Wu, Tao; Yin, Guoyin;Liu, Guosheng*“Palladium-Catalyzed Intramolecular Aminofluorination of Unactivated Alkenes”,J. Am. Chem. Soc.2009,131, 16354-16355.

4.Wu, Liang; Qiu, Shuifa;Liu, Guosheng*“Br？nsted Base-Modulated Regioselective Pd-Catalyzed Intramolecular Aerobic Oxidative Amination of Alkenes:Formation of Seven-Membered Amides and Evidence for Allylic C-H Activation.”Org. Lett.2009,11, 2707.

5.Qiu, Shuifa; Wei, Yunyang;Liu, Guosheng*“Palladium-Catalyzed Intramolecular Hydro- amination of Allenes Coupled to Aerobic Alcohol Oxidation.”Chem. Eur. J.2009,15, 2751.

6. Liu, Guosheng*; Yin, Guoyin; Wu, Liang; “Palladium-catalyzed intermolecular aerobic oxidative amination of terminal alkenes: efficient synthesis of linear allylamine derivatives.”Angew. Chem. Int. Ed.2008,47, 4733.

7.Yin, Guoyin;Liu, Guosheng*“Palladium-catalyzed oxidative cyclization of enyne with hydrogen peroxide as the oxidant.”Angew. Chem. Int. Ed.2008,47, 5442. (Featured in Synfact, 2008, 10, 1066)

8.Wu, Yicheng;Liu, Guosheng*“Palladium-Catalyzed Allylic C-H Bond Functionalization of Olefins”,Top. Cur. Chem.2010(in press).

9.Chai, Jianfang;Liu, Guosheng; Chaicharoen, Kittisak; Wesdemiotis, Chrys; Jia, Li* “Cobalt-Catalyzed Carbonylative Polymerization of Azetidines.”Macromolecules2008,41, 8980.

10. Liu, Guosheng; Stahl, Shannon. S* “Two-Faced Reactivity of Alkenes: cis- versus trans-aminopalladation in Aerobic Pd-Catalyzed Intramolecular Aza-Wacker Reactions.”J. Am. Chem. Soc.2007,129, 6328-6335.

11. Liu, Guosheng; Stahl, Shannon. S* “Highly Regeioselective Pd-Catalyzed Intermolecular Aminoacetoxylation of Alkene and Evidence for the cis-Aminopalladation and SN₂C-O Bond Formation”,J. Am. Chem. Soc.2006,128, 7179-7181.

12. Liu, Guosheng; Jia, Li* “Cobalt-Catalyzed Carbonylative Copolymerizaiton of N-Alkylazetidines and Tetrahydrofuran”,Angw. Chem. Int. Ed.2006,45, 129-131.

13. Liu, Guosheng; Jia, Li* “Design of Catalytic Carbonylative Polymerizations of Heterocylces. Synthesis of Polyesters and Amphiphilic Poly(amide-block-ester)s”,J. Am. Chem. Soc.2004,126, 14716.