Deng, Liang   Professor

State Key Laboratory of Organometallic Chemistry

Shanghai Institute of Organic Chemistry, CAS

345 Lingling Lu, Shanghai 200032

Phone/Fax: +86 21 54925460

Email:deng@sioc.ac.cn

Web:http://dengliang.sioc.ac.cn

Education:

08/2002 - 07/2006  Ph.D. The Chinese University of Hong Kong(Advisor: Prof. Zuowei Xie)

09/1998 - 07/2002  B.S. in chemistry, Peking University.

Research Experience:

08/2009 - present   Professor, State Key Laboratory of OrganometallicChemistry, SIOC

01/2007 - 07/2009　Postdoctoral fellow, Harvard University (Advisor: Prof. R. H. Holm)

08/2006 - 12/2006　Postdoctoral fellow, The Chinese University of Hong Kong (Advisor: Prof. Zuowei Xie)

Awards & Honors:

Organometallics, Associate editor

Advisory board members ofInorganic Chemistry,Chin. Org. Chem.,Chin. Chem. Bull.

Germany Thieme press “Thieme Chemistry Journal Award”（2013）

American Chemical Society “Organometallics Young Investigator Fellows”（2014）

Research Interest:

Organometallic Chemistry of Transition-metals

Small molecule Activation

Organometallic Catalysis

Bioinorganic Chemistry 

Selected Publications:

1.Liu, Yang; Cheng, Jun;Deng, Liang*.Three-Coordinate Formal Cobalt(0), Iron(0), and Manganese(0) Complexes with Persistent Carbene and Alkene Ligation.Acc. Chem. Res.,2020,53,244-254.

2.Wang, Dongyang; Leng, Xuebing; Ye, Shengfa;Deng, Liang*.Substrate Redox Non-innocence Inducing Stepwise Oxidative Addition Reaction: Nitrosoarene C？N Bond Cleavage on Low-Coordinate Cobalt(0) Species.J. Am. Chem. Soc.,2019,141, 7731-7735.

3.Gao, Yafei; Li, Guangyu;Deng, Liang*. Bis(dinitrogen)cobalt(-1) Complexes with NHC Ligation: Synthesis, Characterization, and Their Dinitrogen Functionalization Reactions Affording Side-on Bound Diazene Complexes.J. Am. Chem. Soc.,2018,140, 2239-2250.

4.凡一明；程骏；高亚飞；施敏；邓亮*。硼桥联三氮杂环卡宾配位的铁分子氮配合物：合成、表征和反应性质研究。化学学报，2018,76, 445-452.

5.Liu, Yang;Deng, Liang*. Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes.J. Am. Chem. Soc.,2017,139, 1798-1801.

6.Yao, Xiao-Nan#; Du, Jing-Zhen#; Zhang,Yi-Quan; Leng, Xue-Bing; Yang, Mu-Wen; Jiang, Shang-Da; Wang, Zhen-Xing; Ouyang, Zhong-Wen;Deng, Liang*; Wang, Bing-Wu*; Gao, Song*. Two-Coordinate Co(II) Imido Complexes as Outstanding Single-Molecule Magnets.J. Am. Chem. Soc.,2017,139, 373-380.

7.Wang, Lei; Hu, Lianrui; Zhang, Hezhong; Chen, Hui*;Deng, Liang*. Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity.J. Am. Chem. Soc.,2015,137, 14196-14207.

8.Du, Jingzhen; Wang, Linbo; Xie, Meihua;Deng, Liang*. A Two-Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis, Structure, and Reactivity.Angew. Chem. Int. Ed.,2015,54, 12640-12644.

9.Zhang, Hezhong; Ouyang, Zhenwu; Liu, Yuesheng; Zhang, Qiang;Deng, Liang*. (Aminocarbene)(Divinyltetramethyldisiloxane) Iron(0) Compounds: a Class of Valueable Low-Coordinate Iron(0) Reagents.Angew. Chem. Int. Ed.,2014,53, 8432-8436.

10.Mo, Zhenbo; Xiao, Jie; Gao, Yafei;Deng, Liang*. Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes.J. Am. Chem. Soc.,2014,136, 17414-17417.

11.Zhang, Long; Liu, Yuesheng;Deng, Liang*. Three-Coordinate Cobalt(IV) and Cobalt(V) Imido Complexes with N-Heterocyclic Carbene Ligation: Synthesis, Structure, and Their Distinct Reactivity in C-H Bond Amination.J. Am. Chem. Soc.,2014,136, 15525-15528.

12.Mo, Zhenbo; Liu, Yang;Deng, Liang*. Anchoring of Silyl Donors on a N-Heterocyclic Carbene through the Cobalt-Mediated Silylation of Benzylic C-H Bonds.Angew. Chem. Int. Ed.,2013,52, 10845-10849.