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Han, Xiuling Associate Professor State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS 345 Lingling Lu, Shanghai 200032 Phone: +86 21 54925153 Fax: +86 21 64166128 Email:xlhan@sioc.ac.cn |
Education: |
09/2007 - 07/2010 Ph.D (Supervisor: Prof Xiyan Lu), Suchou University 09/1993 - 07/1996 Master (Chemistry) (Supervisor: Prof Bincai Wu), East China Normal University 09/1989 - 07/1993 B.S. (Chemistry), Nanjing Normal University |
Research Experience: |
06/2006 - present Associate Professor, State Key Laboratory of Organometallic Chemistry, SIOC 06/1999 - 06/2006 Research Associate, State Key Laboratory of Organometallic Chemistry, SIOC 07/1996 - 06/1999 Research Assistant, State Key Laboratory of Organometallic Chemistry, SIOC |
Research Interest: |
Palladium(II)- catalyzed reactions |
Selected Publications: |
1.Wang, H.;Han, X.*; Lu, X.* Pd(II)-Catalyzed Annulation of N-Benzyl-N-Aroylmethyl-2- Alkynamides with Arylboronic Acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-β-Hydroxy-γ-Lactams.Tetrahedron2010,66, 9129-9134. 2.Han, X.; Lu, X.* Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synthesis of Substituted3-Hydroxymethyl Indoles Org. Lett.2010,12, 3336-3339. 3. Han, X.; Lu, X.* Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins Org. Lett.2010,12, 108-111. 4. Han, X.; Lu, X.* Novel Palladium-Catalyzed Acyloxylation/Cyclization of 2-(3’-Alkenyl)indoles.Org. Lett.2009,11, 2381-2384. 5.Feng, J.; Lu, X.*; Kong, A.;Han, X. A Highly Regio- and Stereo-Selective [3+2] Annulation of Allylic Compounds and 2-Substituted1,1-Dicyanoalkenes through a Catalytic Carbon–Phosphorus Ylide Reaction.Tetrahedron2007,63, 6035-6041. 6.Kong, A.;Han, X.; Lu, X.* Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzed Endo-Mode Oxidative Cyclization of 3-(3’-Alkenyl)indoles.Org. Lett.2006,8, 1339-1343. 7. Han, X.; Liu, G.; Lu, X* β-H Elimination on Pd(II)-Catalyzed Reactions.Chinese Journal of Organic Chemistry, 2005,25, 1182-1197. 8.Du, Y.;Han, X.; Lu, X.* Alkaloids-Catalyzed Regio- and Enantioselective Allylic Nucleophilic Substitution of tert-Butyl Carbonate of the Morita-Baylis-Hillman ProductsTetrahedron Lett.2004,45, 4967-4971. 9.Zhang, Q.; Lu, X.;*Han, X.Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4’-Acetoxy-2’-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions.J. Org. Chem.2001,66, 7676-7684.
10.Zhang, Z.; Lu, X.*; Xu, Z.; Zhang, Q.;Han, X.Role of Halide Ions in Divalent Palladium Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon-Palladium Bond.Organometallics2001,20, 3724-3728. |