Han, Xiuling  Associate Professor

State Key Laboratory of Organometallic Chemistry,

Shanghai Institute of Organic Chemistry, CAS

345 Lingling Lu, Shanghai 200032

Phone: +86 21 54925153

Fax: +86 21 64166128

Email:xlhan@sioc.ac.cn

Education:

09/2007 - 07/2010  Ph.D (Supervisor: Prof Xiyan Lu), Suchou University

09/1993 - 07/1996  Master (Chemistry) (Supervisor: Prof Bincai Wu), East China Normal University

09/1989 - 07/1993  B.S. (Chemistry), Nanjing Normal University

Research Experience:

06/2006 - present   Associate Professor, State Key Laboratory of Organometallic Chemistry, SIOC

06/1999 - 06/2006  Research Associate, State Key Laboratory of Organometallic Chemistry, SIOC

07/1996 - 06/1999  Research Assistant, State Key Laboratory of Organometallic Chemistry, SIOC

 

Research Interest:

Palladium(II)- catalyzed reactions

Selected Publications:

1.Wang, H.;Han, X.*; Lu, X.* Pd(II)-Catalyzed Annulation of N-Benzyl-N-Aroylmethyl-2- Alkynamides with Arylboronic Acids: An Efficient Synthesis of Highly Substituted α-Alkylidene-β-Hydroxy-γ-Lactams.Tetrahedron2010,66, 9129-9134.

2.Han, X.; Lu, X.* Cationic Pd(II)-Catalyzed Tandem Reaction of 2-Arylethynylanilines and Aldehydes: An Efficient Synthesis of Substituted3-Hydroxymethyl Indoles Org. Lett.2010,12, 3336-3339.

3. Han, X.; Lu, X.* Control of Chemoselectivity by Counteranions of Cationic Palladium Complexes: A Convenient Enantioselective Synthesis of Dihydrocoumarins Org. Lett.2010,12, 108-111.

4. Han, X.; Lu, X.* Novel Palladium-Catalyzed Acyloxylation/Cyclization of 2-(3’-Alkenyl)indoles.Org. Lett.2009,11, 2381-2384.

5.Feng, J.; Lu, X.*; Kong, A.;Han, X. A Highly Regio- and Stereo-Selective [3+2] Annulation of Allylic Compounds and 2-Substituted1,1-Dicyanoalkenes through a Catalytic Carbon–Phosphorus Ylide Reaction.Tetrahedron2007,63, 6035-6041.

6.Kong, A.;Han, X.; Lu, X.* Highly Efficient Construction of Benzene Ring in Carbazoles by Palladium-Catalyzed Endo-Mode Oxidative Cyclization of 3-(3’-Alkenyl)indoles.Org. Lett.2006,8, 1339-1343.

7. Han, X.; Liu, G.; Lu, X* β-H Elimination on Pd(II)-Catalyzed Reactions.Chinese Journal of Organic Chemistry,  2005,25, 1182-1197.

8.Du, Y.;Han, X.; Lu, X.* Alkaloids-Catalyzed Regio- and Enantioselective Allylic Nucleophilic Substitution of tert-Butyl Carbonate of the Morita-Baylis-Hillman ProductsTetrahedron Lett.2004,45, 4967-4971.

9.Zhang, Q.; Lu, X.;*Han, X.Palladium(II)-Catalyzed Asymmetric Cyclization of (Z)-4’-Acetoxy-2’-butenyl 2-Alkynoates. Role of Nitrogen-Containing Ligands in Palladium(II)-Mediated Reactions.J. Org. Chem.2001,66, 7676-7684.
10.Zhang, Z.; Lu, X.*; Xu, Z.; Zhang, Q.;Han, X.Role of Halide Ions in Divalent Palladium Mediated Reactions: Competition between β-Heteroatom Elimination and β-Hydride Elimination of a Carbon-Palladium Bond.Organometallics2001,20, 3724-3728.